Hydroxide Ion Concentration Equation:
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The hydroxide ion concentration ([OH-]) is a measure of the alkalinity of a solution. It's related to the hydrogen ion concentration ([H+]) through the water dissociation constant (Kw), which is temperature-dependent.
The calculator uses the equation:
Where:
Explanation: The equation shows the inverse relationship between [OH-] and [H+] in aqueous solutions, mediated by the water dissociation constant which varies with temperature.
Details: Calculating hydroxide ion concentration is essential for understanding solution pH, buffer capacity, and chemical reaction conditions in various fields including chemistry, biology, and environmental science.
Tips: Enter hydrogen ion concentration in mol/L and temperature in °C. The calculator will determine Kw at the given temperature and compute [OH-].
Q1: What is the relationship between [OH-] and pH?
A: pH = -log[H+], while pOH = -log[OH-]. In aqueous solutions at 25°C, pH + pOH = 14.
Q2: How does temperature affect Kw?
A: Kw increases with temperature as water dissociation is endothermic. At 25°C, Kw = 1.0×10⁻¹⁴, but at 37°C (body temp), Kw ≈ 2.4×10⁻¹⁴.
Q3: What are typical [OH-] values in common solutions?
A: In neutral water at 25°C, [OH-] = 1×10⁻⁷ M. In 0.1 M NaOH, [OH-] ≈ 0.1 M.
Q4: Can this calculator be used for very high or low temperatures?
A: The calculator uses a simplified temperature adjustment. For extreme temperatures, more precise Kw values should be used.
Q5: How is [OH-] measured experimentally?
A: Common methods include pH meters (converted to [OH-] via Kw), conductivity measurements, or acid-base titration.